Copyright © LightForm Inc, 2012
LightForm Inc: PARISS® Analytical Spectral and Hyperspectral Imaging
To Determine Bandpass and Resolution We Need to Know
The Linear Dispersion At The Wavelength of Interest and The Entrance Slit Width
From equation (3) in the previous slide Linear dispersion
Linear Dispersion is NOT a constant: because the angle of diffraction or
refraction varies with wavelength, linear dispersion also varies with
wavelength. For angles of diffraction or refraction less than ~20 degrees
beta approximates to unity.
For a diffraction grating, this means that linear dispersion is greatest when
wavelengths are longest
For a prism, this means that linear dispersion is greatest when wavelengths
are shortest
Then:
Bandpass = entrance slit width or exit slit width (whichever is greater)
multiplied by linear dispersion at the wavelength of interest. Bandpass and
resolution are given by the Full Width at Half Maximum (FWHM) of an “infinitely
narrow” monochromatic emission line. For most spectrometers the emission lines of
a low pressure Hg lamp satisfies this need.
Resolution = Bandpass when reducing the entrance slit-width no longer results in
a decrease in FWHM. Therefore, Resolution is the instrumental limit of bandpass
If a CCD is used as a detector then the “width of the exit slit” is the total width of the number
of pixels that corresponds to the FWHM of the image of the entrance slit. The optimum FWHM
is three pixels and this should be used to determine the nominal width of the entrance slit.
Mini-tutorial
Grating and Prism
Characteristics